ANALYSIS OF FORMATION AND CHARACTERIZATION OF Ni-TiN-AlN COMPOSITE LAYERS USING ELECTRODEPOSITION METHOD WITH PULSE CURRENT DENSITY VARIATIONS: ANALISIS PEMBENTUKAN DAN KARAKTERISASI LAPISAN KOMPOSIT Ni-TiN-AlN DENGAN METODE ELEKTRODEPOSISI TERHADAP VARIASI RAPAT ARUS PULSA

Syamsinar; Esmar Budi; Teguh Budiprayitno

doi:10.21009/03.1303.FA28

Authors

Syamsinar Program Studi Fisika, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Negeri Jakarta
Esmar Budi Program Studi Fisika, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Negeri Jakarta
Teguh Budiprayitno Program Studi Fisika, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Negeri Jakarta

DOI:

https://doi.org/10.21009/03.1303.FA28

Abstract

In this paper, the formation of a Ni-TiN-AlN composite coating layer is carried out to study the effect of variations in pulse current density on surface morphology and coating composition. The coating process is carried out using the electrodeposition method. The Ni-TiN-AlN composite layer was formed on a Tungsten Carbide (WC) substrate with an electrolyte solution composition consisting of 0.17 M NiCl2.6H2O, 0.38 M NiSO4.6H2O, 0.49 M H3BO3, 0.6 g/l Sodium Dodecyl Sulfate (SDS), particles TiN strengthening powder of 6 gr/l and AlN powder of 10 g/l. Electrodeposition on the substrate was carried out for 30 minutes and variations in current density used were 0.15 mA/mm2, 0.25 mA/mm2, and 0.35 mA/mm2. The Ni-TiN-AlN composite layer was characterized using SEM-EDS (Scanning Electron Microscopy-Energy Dispersive Spectroscopy), X-Ray Diffraction (XRD), and Hardness Test (Vickers). The results show that the surface morphology and composition of the Ni-TiN-AlN composite layer are influenced by the current density used.

References

[1] E. Budi et al., “Crystal Structure and Corrosion of Electrodeposited Ni-TiAlN Composite Coatings,” Journal of Technology and Social Science (JTSS), vol. 1, pp. 54-61, 2017.

[2] Z. Yang et al., “Study on Characteristics and Microstructure of Ni-AlN Thin Coatings Prepared via Different Electrodeposition Techniques,” International Journal of Electrochemical Science, vol. 17, pp. 1-12, 2022.

[3] D. K. Rahman, E. Budi, H. Nasbey, “Kajian Pengaruh Variasi Temperatur Terhadap Struktur Kristal Berbagai Lapisan Komposit Nikel,” in Prosiding Seminar Nasional Fisika, 2020.

[4] Z. Yang et al., “Study on Characteristics and Microstructure of Ni-AlN Thin Coatings Prepared via Different Electrodeposition Techniques,” International Journal of Electrochemical Science, vol. 17, pp. 1-12, 2022.

[5] A. Zoikis-Karathanasis, E. A. Pavlatou, N. Spyrellis, “Pulse Electrodeposition of Ni–P Matrix Composite Coatings Reinforced by SiC Particles,” Journal of Alloys and Compounds, vol. 494, no. 1-2, pp. 396-403, 2010.

[6] S. A. Lajevardi, T. Shahrabi, “Effects of Pulse Electrodeposition Parameters on the Properties of Ni–TiO2 Nanocomposite Coatings,” Applied Surface Science, vol. 256, no. 22, pp. 6775-6781, 2010.

[7] R. R. Saputra, S. Oediyani, Y. Lestari, and E. Mabruri, “Pengaruh Rapat Arus dan Waktu Pelapisan Nikel Pada AISI 410 dengan Metode Pulse Electrodeposition Terhadap Struktur Mikro dan Laju Korosi,” Mater. Metal., vol. 2, 2017, pp. 77–82.

[8] B. Esmar et al., “Komposisi dan Morfologi Permukaan Lapisan Komposit Ni-TiN-AlN Elektrodeposisi Prosiding Bidang Fisika, pp. 348-353, 2015.

[9] H. Maharana, B. Bishoyi, A. Basu, “Current density dependent microstructure and texture evolution and texture evolution related effects on properties of electrodeposited Ni-Al coating,” Journal of Alloys and Compounds, vol. 787, pp. 483-494, 2019.

[10] Sujatno, A., Salam, R., Bandriyana, & Dimyati, A. (2015). Studi Scanning Electron Microscopy (SEM) untuk Karakterisasi Proses Oxidasi Paduan Zirkonium. Jurnal Forum Nuklir (JFN), 9(2), 44-50.

[11] F. Hidayanti, A. A. Harnovan, “Application Of Scanning Electron Microscopy: A Review,” International Journal of Applied Science and Engineering Review, vol. 1, no. 6, pp. 91-102, 2020.

[12] A. W. Andiani, E. Budi, I. Sugihartono, “Pembentukan Lapisan Komposit Ni-TiAlN/Si3N4 menggunakan Metode Elektrodeposisi dengan Variasi Temperatur,” Prosiding Seminar Nasional Fisika(E-JOURNAL),vol.8,pp.SNF2019145,2019,doi:https://doi.org/10.21009/03.SNF2019.02.PA.20.

[13] N. Parhizkar et al., “Electrochemical Deposition of Ni-TiN Nanocomposite Coatings and the Effect of Sodium Dodecyl Sulphate Surfactant on the Coating Properties,” Bulletin of Materials Science, vol. 39, no. 4, pp. 1021-1027, 2016.

[14] Nafise Parhizkar et al., “Electrochemical Deposition of Ni–TiN Nanocomposite Coatings and the Effect of Sodium Dodecyl Sulphate Surfactant on the Coating Properties,” vol. 39, no. 4, pp. 1021-1027, 2016, doi: https://doi.org/10.1007/s12034-016-1238-3.

[15] B. Li et al., “Ultrasonic-Assisted Electrodeposition of Ni-Cu/TiN Composite Coating from Sulphate-Citrate Bath: Structural and electrochemical properties,” Ultrasonics Sonochemistry, vol. 58, p. 104680, 2019.

[16] P. Wang et al., “Novel Nitride Materials Synthesized at High Pressure,” Crystals, vol. 11, no. 6, p. 614, May 2021, doi: https://doi.org/10.3390/cryst11060614.

[17] D. Tonelli, E. Scavetta, I. Gualandi, “Electrochemical Deposition of Nanomaterials for Electrochemical Sensing,” Sensors, vol. 19, no. 5, p. 1186, 2019, doi: https://doi.org/10.3390/s19051186

[18] M. F. Gazulla et al., “Nitrogen Determination by SEM‐EDS and Elemental Analysis,” X‐Ray Spectrometry, vol. 42, no. 5, pp. 394-401, 2013.