Geochemical and Magnetic Suseptibility Analysis for Critical Minerals Detection in Igneous Rocks and Beach Sand
DOI:
https://doi.org/10.21009/SPEKTRA.093.04Keywords:
critical minerals, Lenggoksono, REE, magnetic susceptibilityAbstract
Critical minerals are an important natural resource that will continue to be necessary for modern industries. This study aims to determine the distribution of critical minerals based on geochemical data and magnetic susceptibility. Samples were taken from Lenggoksono beach, Southern Malang. The determination of chemical elements was conducted using X-ray fluorescence (XRF). Rare Earth Elements (REE) were identified using Inductively Coupled Plasma–Optical Emission Spectrometry (ICP-OES). Magnetic susceptibility measurements were carried out using a Barrington Magnetic Susceptibility Meter (MS2B). The results showed that the dominant elements were Silica Oxide, SiO2 (70 Wt%), Iron Oxide, Fe2O3 (14.05 Wt%), and Calcium Oxide CaO (5.57 Wt%), which were categorized as critical minerals. The average REE elements detected were Cerium, Ce (6.75 mg/kg), Gadolinium, Gd (5.98 mg/kg), Neodymium, Nd (13.56 mg/kg), Praseodymium, Pr (6.62 mg/kg), Terbium, Tb (5.57 mg/kg), and Yttrium, Y (10.98 mg/kg). The magnetic susceptibility ranges from 13.27 to 4143.47 × 10-8m3/kg. Pearson’s Correlation analysis revealed a significant correlation between low-frequency magnetic susceptibility (ꭓlf) and high-frequency magnetic susceptibility (ꭓhf) with a significance level of 0.01. ꭓlf and ꭓhf also showed a significant correlation with Gd, with a correlation value of R² = 0.84 and a significance level of 0.05. These results indicate that the presence of one critical mineral can serve as a clue to the presence of other critical minerals, and magnetic susceptibility can be used as a proxy indicator for critical minerals in natural materials.
References
D. B. Agusdinata, H. Eakin, and W. Liu, “Critical minerals for electric vehicles: A telecoupling review,” Environmental Research Letters, vol. 17, no. 2, p. 013005, 2022, DOI: 10.1088/1748-9326/ac4763.
I. D. Qurbani, R. J. Heffron, and A.T.S. Rifano, “Justice and critical mineral development in Indonesia and across ASEAN,” The Extractive Industries and Society, vol. 8, no.1, pp. 355-362, 2021, DOI: 10.1016/j.exis.2020.11.017.
B. A. Aziz, “Mineral Kritikal dari Perspektif Keselamatan Negara: Critical Minerals from a National Security Perspective,” International Journal of Interdisciplinary and Strategic Studies, vol.2, no.3, pp. 145-156, 2021, DOI: 10.47548/ijistra.2021.38.
A. Tonggiroh, “The Geochemical Character of Trace Elements in Coastal Sediments: Potential Implications of Metallic Mineral Resources on the West Coast of South Sulawesi, Indonesia,” Journal of Hunan University Natural Sciences, vol/50, no.5, 2023, DOI: 10.55463/issn.1674-2974.50.5.8.
N. A. Sasongko et al., “Trend of critical minerals utilization for Indonesia’s Sustainable Energy Transition: A review,” in E3S Web of Conferences vol. 513, p. 04004, EDP Sciences, 2024, DOI: 10.1051/e3sconf/202451304004.
M. Arienzo et al., “Advances in the fate of rare earth elements, REE, in transitional environments: coasts and estuaries,” Water, vol.14, no.3, p. 401, 2022, DOI: 10.3390/w14030401.
I. A. R. Saputra, S. Aritonang, and M.D.M. Manessa, M. D. M., “Pemetaan Sumber Daya Rare Earth Elements (REE) Untuk Bahan Baku Industri Pertahanan dengan Metode Eksplorasi Geomarine,” Teknologi Penginderaan, vol.1, no.1, 2019, DOI: 10.33172/tp.v1i1.483.
C. Reimann et al., “GEMAS: Establishing geochemical background and threshold for 53 chemical elements in European agricultural soil,” Applied geochemistry, 88, 302-318, 2018, DOI: 10.1016/j.apgeochem.2017.01.021.
V. Balaram, “Advances in analytical techniques and applications in exploration, mining, extraction, and metallurgical studies of rare earth elements,” Minerals, vol.13, no.8, p. 1031, 2023, DOI: 10.3390/min13081031.
A. Susilo et al., “Inventory and identification of geodiversity to support geotourism in the Lenggoksono bay area of South Malang, Indonesia,” in Journal of Physics: Conference Series vol. 1816, no. 1, p. 012111 IOP Publishing, 2021, DOI: 10.1088/1742-6596/1816/1/012111.
S. John et al., “Earth Surface Processes, Landforms and Sediment Deposits: Rivers, alluvial plains, and fans,” pp. 365-461, 2008, DOI: 10.1017/CBO9780511805516.014.
S. Samsidar et al., “X-Ray Fluorescence Monitoring Metal Content and Nutrient Elements for Predicting Soil Fertility Parameters Based on pH in Ultisol Soil,” International Journal of Hydrological and Environmental for Sustainability, vol.2, no.3, pp.104-112, 2023, DOI: 10.58524/ijhes.v2i3.290.
M. Lucie, A. Francis, and Macdonald, “Petrography and Geochemistry of the Intrusive Rocks at the Diorite-Hosted Regnault Au Mineralization,” Minerals, 12(2):128-128, 2022, DOI: 10.3390/min12020128.
C. Maame et al., “ Determination of trace elements and macronutrients in agricultural soils using energy dispersive X-ray fluorescence as a rapid and precise analytical technique,” The EGU General Assembly, p.9564, 2020, DOI: 10.5194/EGUSPHERE-EGU2020-9564.
V. Daniel et al., “Relating magnetic properties of municipal solid waste constituents to iron content – implications for enhanced landfill mining,” vol.8, no.8, pp.31-46, 2019, DOI: 10.31025/2611-4135/2019.13876.
N. Sharma et al., “Analysis of mineral elements in medicinal plant samples using LIBS and ICP-OES,” At. Spectrosc, vol. 41, no.6, pp.234-241, 2020, DOI: 10.46770/AS.2020.06.003.
S. R. Khan et al., “Inductively coupled plasma optical emission spectrometry (ICP-OES): a powerful analytical technique for elemental analysis,” Food Analytical Methods, pp. 1-23, 2022, DOI: 10.1007/s12161-021-02148-4.
C. Morrison et al., “Methods for the ICP-OES analysis of semiconductor materials,” Chemistry of Materials, vol. 32, no. 5, pp.1760-1768, 2020, DOI: 10.1021/acs.chemmater.0c00255.
Y. Han et al., “Fault monitoring using novel adaptive kernel principal component analysis integrating grey relational analysis,” Process Safety and Environmental Protection, vol.157, pp.397-410, 2022, DOI: 10.1016/j.psep.2021.11.029.
C. Liu et al., “Element case studies: rare earth elements,” Agromining: farming for metals: extracting unconventional resources using plants, pp.471-483, 2021, DOI: 10.1007/978-3-030-58904-2_24.
L. S. Xiao, ”Scattered and Rare Earth Metals,” in Membrane-Based Separations in Metallurgy, pp. 205-225 Elsevier, 2017, DOI: 10.1016/B978-0-12-803410-1.00007-4.
K.R. Long et al., “The principal rare earth elements deposits of the United States: A summary of domestic deposits and a global perspective,” Springer Netherlands, pp. 131-155, 2012, DOI: 10.1007/978-90-481-8679-2_7.
P. L. Verplanckand M. W. Hitzman, “Rare earth and critical elements in ore deposits,” Society of Economic Geologists, 2016, DOI: 10.5382/REV.18.
J. A. Dearing, J. A. Environmental magnetic susceptibility: using the Bartington MS2 system. Chi Pub. 1994.
Q. Liu et al., “Environmental magnetism: Principles and applications,” Reviews of Geophysics, vol.50, no.4, 2012, DOI: 10.1029/2012RG000393.
H. Pan et al., “Pearson correlation coefficient-based pheromone refactoring mechanism for multi-colony ant colony optimization,” Applied Intelligence, vol.51, pp.752-774, 2021, DOI: 10.1007/s10489-020-01841-x.
K. Okoye and S. Hosseini, “Correlation tests in R: pearson cor, kendall’s tau, and spearman’s rho,” in R Programming: Statistical Data Analysis in Research, pp.247-277 Singapore: Springer Nature Singapore, 2024, DOI: 10.1007/978-981-97-3385-9_12.
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Copyright (c) 2024 Yensi Hariyanto, Siti Zulaikah, Cahyo Aji Hapsoro, Shofi Maulida, Hanif 'Izzudin Zakly, Nordiana Mohd Muztaza, Daeng Achmad Suadi, Aditya Pratama, Hamdi Hamdi
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